配位化合物催化活化小分子;金属有机催化氮杂环化合物的合成
黄德光,男,博士,研究员。1999年获武汉大学学士学位;1999-2004在中国科学院福建物构所刘秋田课题组工作,从事生物酶锰簇化合物的合成研究,2003年7月获硕士学位。 2004-2008年在海外学习,并于2008年获理学博士学位。2008-2012年在海外工作从事博士后研究,开展一氧化碳脱氢酶活性中心[Ni(II)-OH-Fe(II)]结构的化学合成,以及相关化合物活化二氧化碳气体的动力学研究,探索反应机理。2012年9月回国,在中国科学院福建物质结构研究所,开展生物酶催化功能模拟研究和活化气体小分子的研究工作,主持了国家自然科学基金面上项目“一氧化碳脱氢酶的功能模拟与二氧化碳小分子的活化”和福建省自然科学基金面上项目“非金属离子活化不饱和烃碳碳键的断裂与重组”等。目前已经在PNAS, J.Am.Chem.Soc., Green Chemistry, ChemSusChem, Org. Lett., Inorg. Chem. Front., Org. Chem. Front., Chem.Commun.等国际主流化学刊物上以发表论文多篇。
1. X. Zhang, Y. Li, W. Fan, D. Huang*, Direct transformation of nitriles to cyanide using chloride anion as catalyst, Chemical Communications, 2024, 60, 2058-2061.
2. Y. Li, J. Jin, W. Fan*, D. Huang*, Strategy for the π-Extension of Indoles Using Acrolein as An Ideal Linker: Simple Synthesis of Indolo[3,2-a]carbazole-6- carbaldehydes and Racemosin B,Organic Letters, 2023, 25, 8284-8289.
3. W. Fan, S. Xiang, Y. Li, W. Zhang, S. Guo, D. Huang*, Iodine Mediated Pyridine Ring Expansion for the Construction of Azepines, Organic Letters, 2022, 24, 2075-2080.
4. W. Fan, Y. Zhang, Y. Li, W. Zhang, D. Huang*, Solvent-free Strategy for Direct Access to Versatile Quaternary Ammonium Salts with Complete Atom Economy, ChemSusChem, 2022, 15, e202200529.
5. S. Xiang, W. Fan, W. Zhang, Y. Li, S. Guo, D. Huang*, Aqueous CO2 fixation: construction of pyridine skeletons in cooperation with ammonium cations, Green Chemistry, 2021, 23, 7950-7955.
6. Y. Li, W. Fan, Z. Zhang, X. Xie, S. Xiang, D. Huang*, Copper(II)–hydroxide facilitated C–C bond formation: the carboxamido pyridine system versus the methylimino pyridine system, Dalton Transactions, 2020, 49, 12189-12197.
7. S. Xiang, W. Fan, W. Zhang, Y. Li, S. Guo, D. Huang*, Copper(II) facilitated decarboxylation for the construction of pyridyl-pyrazole skeletons, Inorganic Chemistry Frontiers, 2019, 6, 2359-2364.
8. Y. Li, W. Fan, Z. Zhang, X. Xie, S. Xiang, D. Huang*, Utilization of nitriles as the nitrogen source: practical and economical construction of 4-aminopyrimidine and β-enaminonitrile skeletons, Organic Chemistry Frontiers, 2019, 6, 3071-3077.
9. X. Zhang, Z. Zhang, S. Xiang, Y. Zhu, C. Chen, D. Huang*, Base induced C–CN bond cleavage at room temperature: a convenient method for the activation of acetonitrile, Inorganic Chemistry Frontiers, 2019, 6, 1135-1140.
10. Y. Wang, X. Zhang, H. Liu, H. Chen, D. Huang*, Nickel-catalyzed direct formation of the C-S bonds of aryl sulfides from arylsulfonyl chlorides and aryl iodides using Mn as a reducing agent, Organic Chemistry Frontiers, 2017, 4, 31-36.
11. D. Huang, O. V. Makhlynets, L. L. Tan, S. C. Lee, E. V. Rybak-Akimova, R. H. Holm*, Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction, Proceedings of the National Academy of Sciences of the United States of America, 2011, 108, 1222-1227.
12. D. Huang, R. H. Holm*,Reactions of the Terminal NiII–OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular NiIIFeII Bridged Site, Journal of American Chemical Society, 2010, 132, 4693-4701.
13. D. Huang, A. J. Blake, E. J. L. McInnes, J. McMaster, E. S. Davies, C. Wilson, J. Wolowska, M. Schröder*, Electronic structure of the mononuclear Ag(II) complex [Ag([18]aneS4O2)]2+ ([18]aneS4O2 = 1,10-dioxa-4,7,13,16-tetrathiacyclooctadecane), Chemical Communications, 2008, 1305-1307.
14. D. Huang, X. Zhang, C. Ma, H. Chen, C. Chen, Q. Liu*, C. Zhang, D. Liao,L. Li, Aggregation of tetranuclear Mn building blocks with alkali ion. Syntheses, crystal structures and chemical behaviours of monomer, dimmer and polymer containing [Mn4(µ3-O)2]8+ units, Dalton Transactions, 2007, 680-688.